In 1917 Albert Einstein, in his paper Zur Quantentheorie der Strahlung (On the Quantum Theory of Radiation), laid the foundation for the invention of the laser and its predecessor, the maser, in a ground-breaking rederivation of Max Planck's law of radiation based on the concepts of probability coefficients (later to be termed 'Einstein coefficients') for the absorption, spontaneous emission, and stimulated emission of electromagnetic radiation.
In 1928, Rudolph W. Landenburg confirmed the existence of stimulated emission and negative absorption.[6] In 1939, Valentin A. Fabrikant predicted the use of stimulated emission to amplify "short" waves.[7]
In 1947, Willis E. Lamb and R. C. Retherford found apparent stimulated emission in hydrogen spectra and made the first demonstration of stimulated emission.[8]
In 1950, Alfred Kastler (Nobel Prize for Physics 1966) proposed the method of optical pumping, which was experimentally confirmed by Brossel, Kastler and Winter two years later.[9]
The first working laser was demonstrated on 16 May 1960 by Theodore Maiman at Hughes Research Laboratories.[10] Since then, lasers have become a multi-billion dollar industry. By far the largest single application of lasers is in optical storage devices such as compact disc and DVD players,[citation needed] in which a semiconductor laser less than a millimeter wide scans the surface of the disc. The second-largest application is fiber-optic communication. Other common applications of lasers are bar code readers, laser printers and laser pointers.
Maser
In 1953, Charles H. Townes and graduate students James P. Gordon and Herbert J. Zeiger produced the first microwave amplifier, a device operating on similar principles to the laser, but amplifying microwave rather than infrared or visible radiation. Townes's maser was incapable of continuous output. Nikolay Basov and Aleksandr Prokhorov of the Soviet Union worked independently on the quantum oscillator and solved the problem of continuous output systems by using more than two energy levels and produced the first maser. These systems could release stimulated emission without falling to the ground state, thus maintaining a population inversion. In 1955 Prokhorov and Basov suggested an optical pumping of multilevel system as a method for obtaining the population inversion, which later became one of the main methods of laser pumping.
Townes reports that he encountered opposition from a number of eminent colleagues who thought the maser was theoretically impossible -- including Niels Bohr, John von Neumann, Isidor Rabi, Polykarp Kusch, and Llewellyn H. Thomas[1].
Townes, Basov, and Prokhorov shared the Nobel Prize in Physics in 1964 "For fundamental work in the field of quantum electronics, which has led to the construction of oscillators and amplifiers based on the maser-laser principle".
Laser
In 1957, Charles Hard Townes and Arthur Leonard Schawlow, then at Bell Labs, began a serious study of the infrared laser. As ideas were developed, infrared frequencies were abandoned with focus on visible light instead. The concept was originally known as an "optical maser". Bell Labs filed a patent application for their proposed optical maser a year later. Schawlow and Townes sent a manuscript of their theoretical calculations to Physical Review, which published their paper that year (Volume 112, Issue 6).
The first page of Gordon Gould's laser notebook in which he coined the acronym LASER and described the essential elements for constructing one.
At the same time Gordon Gould, a graduate student at Columbia University, was working on a doctoral thesis on the energy levels of excited thallium. Gould and Townes met and had conversations on the general subject of radiation emission. Afterwards Gould made notes about his ideas for a "laser" in November 1957, including suggesting using an open resonator, which became an important ingredient of future lasers.
In 1958, Prokhorov independently proposed using an open resonator, the first published appearance of this idea. Schawlow and Townes also settled on an open resonator design, apparently unaware of both the published work of Prokhorov and the unpublished work of Gould.
The term "laser" was first introduced to the public in Gould's 1959 conference paper "The LASER, Light Amplification by Stimulated Emission of Radiation".[1][11] Gould intended "-aser" to be a suffix, to be used with an appropriate prefix for the spectrum of light emitted by the device (x-rays: xaser, ultraviolet: uvaser, etc.). None of the other terms became popular, although "raser" was used for a short time to describe radio-frequency emitting devices.
Gould's notes included possible applications for a laser, such as spectrometry, interferometry, radar, and nuclear fusion. He continued working on his idea and filed a patent application in April 1959. The U.S. Patent Office denied his application and awarded a patent to Bell Labs in 1960. This sparked a legal battle that ran 28 years, with scientific prestige and much money at stake. Gould won his first minor patent in 1977, but it was not until 1987 that he could claim his first significant patent victory when a Federal judge ordered the government to issue patents to him for the optically pumped laser and the gas discharge laser.
The first working laser was made by Theodore H. Maiman in 1960[12] at Hughes Research Laboratories in Malibu, California, beating several research teams including those of Townes at Columbia University, Arthur Schawlow at Bell Labs,[13] and Gould at a company called TRG (Technical Research Group). Maiman used a solid-state flashlamp-pumped synthetic ruby crystal to produce red laser light at 694 nanometres wavelength. Maiman's laser, however, was only capable of pulsed operation due to its three-level pumping scheme.
Later in 1960 the Iranian physicist Ali Javan, working with William R. Bennett and Donald Herriot, made the first gas laser using helium and neon. Javan later received the Albert Einstein Award in 1993.
The concept of the semiconductor laser diode was proposed by Basov and Javan. The first laser diode was demonstrated by Robert N. Hall in 1962. Hall's device was made of gallium arsenide and emitted at 850 nm in the near-infrared region of the spectrum. The first semiconductor laser with visible emission was demonstrated later the same year by Nick Holonyak, Jr. As with the first gas lasers, these early semiconductor lasers could be used only in pulsed operation, and indeed only when cooled to liquid nitrogen temperatures (77 K).
In 1970, Zhores Alferov in the Soviet Union and Izuo Hayashi and Morton Panish of Bell Telephone Laboratories independently developed laser diodes continuously operating at room temperature, using the heterojunction structure.
Recent innovations
Graph showing the history of maximum laser pulse intensity throughout the past 40 years.
Since the early period of laser history, laser research has produced a variety of improved and specialized laser types, optimized for different performance goals, including:
* new wavelength bands
* maximum average output power
* maximum peak output power
* minimum output pulse duration
* maximum power efficiency
* maximum charging
* maximum firing
* minimum cost
and this research continues to this day.
Lasing without maintaining the medium excited into a population inversion, was discovered in 1992 in sodium gas and again in 1995 in rubidium gas by various international teams. This was accomplished by using an external maser to induce "optical transparency" in the medium by introducing and destructively interfering the ground electron transitions between two paths, so that the likelihood for the ground electrons to absorb any energy has been cancelled.
Types and operating principles
For a more complete list of laser types see this list of laser types.
Spectral output of several types of lasers.
Gas lasers
Gas lasers using many gases have been built and used for many purposes.
The helium-neon laser (HeNe) emits at a variety of wavelengths and units operating at 633 nm are very common in education because of its low cost.
Carbon dioxide lasers can emit hundreds of kilowatts[14] at 9.6 µm and 10.6 µm, and are often used in industry for cutting and welding. The efficiency of a CO2 laser is over 10%.
Argon-ion lasers emit light in the range 351-528.7 nm. Depending on the optics and the laser tube a different number of lines is usable but the most commonly used lines are 458 nm, 488 nm and 514.5 nm.
A nitrogen transverse electrical discharge in gas at atmospheric pressure (TEA) laser is an inexpensive gas laser producing UV Light at 337.1 nm.[15]
Metal ion lasers are gas lasers that generate deep ultraviolet wavelengths. Helium-silver (HeAg) 224 nm and neon-copper (NeCu) 248 nm are two examples. These lasers have particularly narrow oscillation linewidths of less than 3 GHz (0.5 picometers),[16] making them candidates for use in fluorescence suppressed Raman spectroscopy.
Chemical lasers
Chemical lasers are powered by a chemical reaction, and can achieve high powers in continuous operation. For example, in the Hydrogen fluoride laser (2700-2900 nm) and the Deuterium fluoride laser (3800 nm) the reaction is the combination of hydrogen or deuterium gas with combustion products of ethylene in nitrogen trifluoride. They were invented by George C. Pimentel.
Excimer lasers
Excimer lasers are powered by a chemical reaction involving an excited dimer, or excimer, which is a short-lived dimeric or heterodimeric molecule formed from two species (atoms), at least one of which is in an excited electronic state. They typically produce ultraviolet light, and are used in semiconductor photolithography and in LASIK eye surgery. Commonly used excimer molecules include F2 (fluorine, emitting at 157 nm), and noble gas compounds (ArF [193 nm], KrCl [222 nm], KrF [248 nm], XeCl [308 nm], and XeF [351 nm]).[17]
Solid-state lasers
A 50 W FASOR, based on a Nd:YAG laser, used at the Starfire Optical Range.
Solid-state laser materials are commonly made by "doping" a crystalline solid host with ions that provide the required energy states. For example, the first working laser was a ruby laser, made from ruby (chromium-doped corundum). The population inversion is actually maintained in the "dopant", such as chromium or neodymium. Formally, the class of solid-state lasers includes also fiber laser, as the active medium (fiber) is in the solid state. Practically, in the scientific literature, solid-state laser usually means a laser with bulk active medium, while wave-guide lasers are caller fiber lasers.
"Semiconductor lasers" are also solid-state lasers, but in the customary laser terminology, "solid-state laser" excludes semiconductor lasers, which have their own name.
Neodymium is a common "dopant" in various solid-state laser crystals, including yttrium orthovanadate (Nd:YVO4), yttrium lithium fluoride (Nd:YLF) and yttrium aluminium garnet (Nd:YAG). All these lasers can produce high powers in the infrared spectrum at 1064 nm. They are used for cutting, welding and marking of metals and other materials, and also in spectroscopy and for pumping dye lasers. These lasers are also commonly frequency doubled, tripled or quadrupled to produce 532 nm (green, visible), 355 nm (UV) and 266 nm (UV) light when those wavelengths are needed.
Ytterbium, holmium, thulium, and erbium are other common "dopants" in solid-state lasers. Ytterbium is used in crystals such as Yb:YAG, Yb:KGW, Yb:KYW, Yb:SYS, Yb:BOYS, Yb:CaF2, typically operating around 1020-1050 nm. They are potentially very efficient and high powered due to a small quantum defect. Extremely high powers in ultrashort pulses can be achieved with Yb:YAG. Holmium-doped YAG crystals emit at 2097 nm and form an efficient laser operating at infrared wavelengths strongly absorbed by water-bearing tissues. The Ho-YAG is usually operated in a pulsed mode, and passed through optical fiber surgical devices to resurface joints, remove rot from teeth, vaporize cancers, and pulverize kidney and gall stones.
Titanium-doped sapphire (Ti:sapphire) produces a highly tunable infrared laser, commonly used for spectroscopy as well as the most common ultrashort pulse laser.
Thermal limitations in solid-state lasers arise from unconverted pump power that manifests itself as heat and phonon energy. This heat, when coupled with a high thermo-optic coefficient (dn/dT) can give rise to thermal lensing as well as reduced quantum efficiency. These types of issues can be overcome by another novel diode-pumped solid-state laser, the diode-pumped thin disk laser. The thermal limitations in this laser type are mitigated by utilizing a laser medium geometry in which the thickness is much smaller than the diameter of the pump beam. This allows for a more even thermal gradient in the material. Thin disk lasers have been shown to produce up to kilowatt levels of power.
